A thermionic energy converter is a device consisting of two electrodes placed near one another in a vacuum. One electrode is normally called the cathode, or emitter, and the other is called the anode, or plate. Ordinarily, electrons in the cathode are prevented from escaping from the surface by a potential-energy barrier. When an electron starts to move away from the surface, it induces a corresponding positive charge in the material, which tends to pull it back into the surface. To escape, the electron must somehow acquire enough energy to overcome this energy barrier. At ordinary temperatures, almost none of the electrons can acquire enough energy to escape. However, when the cathode is very hot, the electron energies are greatly increased by thermal motion. At sufficiently high temperatures, a considerable number of electrons are able to escape. The liberation of electrons from a hot surface is called thermionic emission.
The electrons that have escaped from the hot cathode form a cloud of negative charges near it called a space charge. If the plate is maintained positive with respect to the cathode by a battery, the electrons in the cloud are attracted to it. As long as the potential difference between the electrodes is maintained, there will be a steady current flow from the cathode to the plate.
The simplest example of a thermionic device is a vacuum tube diode in which the only electrodes are the cathode and plate, or anode, as shown in Figure 17. The diode can be used to convert alternating current (AC) flow to a pulsating direct current (DC) flow.